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The Solvent Effect on Weak Interactions in Supramolecular Polymers: Differences between Small Molecular Probes and Supramolecular Polymers.
https://tus.repo.nii.ac.jp/records/3632
https://tus.repo.nii.ac.jp/records/36329d7ee5f7-3020-4d2d-b05e-a629207b9280
| 名前 / ファイル | ライセンス | アクション |
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Solvent effect MiniRev ChemPlusChem Accepted Manuscript.pdf (1005 KB)
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| Item type | 学術雑誌論文 / Journal Article(1) | |||||||||||
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| 公開日 | 2021-02-16 | |||||||||||
| タイトル | ||||||||||||
| タイトル | The Solvent Effect on Weak Interactions in Supramolecular Polymers: Differences between Small Molecular Probes and Supramolecular Polymers. | |||||||||||
| 言語 | ||||||||||||
| 言語 | eng | |||||||||||
| キーワード | ||||||||||||
| 主題 | Aggregation, pi interactions, porphyrinoids, solvet effects, supramolecuar chemistry | |||||||||||
| 資源タイプ | ||||||||||||
| 資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||||||||
| 資源タイプ | journal article | |||||||||||
| アクセス権 | ||||||||||||
| アクセス権 | open access | |||||||||||
| アクセス権URI | http://purl.org/coar/access_right/c_abf2 | |||||||||||
| 著者 |
佐竹, 彰治
× 佐竹, 彰治
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| 抄録 | ||||||||||||
| 内容記述タイプ | Abstract | |||||||||||
| 内容記述 | In this minireview, weak interactions that occur in supramolecular polymers are discussed. Combination of weak and strong interactions plays an important role in the construction of supramolecular polymers. It is beneficial to separate the contributions of the weak interactions, as well as each solvent effect on the weak interactions. However, it is generally difficult to observe each solvent effect separately at work in each interaction. Small molecular probes are useful to estimate the contributions of the weak interaction. But, the results should be treated with caution when applied to supramolecular polymer systems. To overcome the problems, a new solvent parameter, solvation ability (SA), is introduced, which was determined on the balance point of extended and stacked forms of porphyrin-based interconvertible supramolecular polymers. | |||||||||||
| 内容記述 | ||||||||||||
| 内容記述 | In this minireview, weak interactions that occur in supramolecular polymers are discussed. Combination of weak and strong interactions plays an important role in the construction of supramolecular polymers. It is beneficial to separate the contributions of the weak interactions, as well as each solvent effect on the weak interactions. However, it is generally difficult to observe each solvent effect separately at work in each interaction. Small molecular probes are useful to estimate the contributions of the weak interaction. But, the results should be treated with caution when applied to supramolecular polymer systems. To overcome the problems, a new solvent parameter, solvation ability (SA), is introduced, which was determined on the balance point of extended and stacked forms of porphyrin-based interconvertible supramolecular polymers. | |||||||||||
| 書誌情報 |
ChemPlusChem 巻 85, 号 7, p. 1542-1548 |
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| 出版者 | ||||||||||||
| 出版者 | Wiley | |||||||||||
| ISSN番号 | ||||||||||||
| 収録物識別子タイプ | PISSN | |||||||||||
| 収録物識別子 | 2192-6506 | |||||||||||
| PubMed番号 | ||||||||||||
| 関連タイプ | isVersionOf | |||||||||||
| 識別子タイプ | PMID | |||||||||||
| 関連識別子 | 32697033 | |||||||||||
| 固有識別子 | ||||||||||||
| 関連タイプ | isVersionOf | |||||||||||
| 識別子タイプ | DOI | |||||||||||
| 関連識別子 | 10.1002/cplu.202000400 | |||||||||||
| 権利 | ||||||||||||
| 言語 | en | |||||||||||
| 権利情報 | The full-text file will be made open to the public on 22 July 2022 in accordance with publisher's 'Terms and Conditions for Self-Archiving'. This is not the published version. Please cite only the published version. | |||||||||||
| 著者版フラグ | ||||||||||||
| 出版タイプ | AM | |||||||||||
| 出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa | |||||||||||
