{"created":"2023-06-19T09:33:18.994649+00:00","id":3631,"links":{},"metadata":{"_buckets":{"deposit":"8ca87d1b-0d8a-4de1-9aa5-981e5d29c6f1"},"_deposit":{"created_by":12,"id":"3631","owners":[12],"pid":{"revision_id":0,"type":"depid","value":"3631"},"status":"published"},"_oai":{"id":"oai:tus.repo.nii.ac.jp:00003631","sets":["401:402"]},"author_link":[],"item_10001_biblio_info_7":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2020-01-13","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"3","bibliographicPageEnd":"684","bibliographicPageStart":"669","bibliographicVolumeNumber":"26","bibliographic_titles":[{"bibliographic_title":"Chemistry - A European Journal","bibliographic_titleLang":"en"}]}]},"item_10001_description_5":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"Bis(imidazolylporphyrinatozinc) molecules linked through a 1,3-butadiynylene moiety respond to the solvents they are dissolved in to afford exclusively extended (E) or stacked (S) supramolecular polymers. This system is expected to be a solvation/desolvation indicator. However, the principles underlying the solvent-dependent formation of the two types of polymers and the mechanism of the transformation between them are unclear. The formation of the polymers is considered to depend on the two types of complementary coordination bonds that can be formed and the π-π interactions between the porphyrins. In this study, the contributions and solvent dependence of both the coordination bonds and the π-π interactions have been investigated. The results clearly indicate that the coordination bonds are weakly or little solvent-dependent, and that the π-π interactions function effectively only in the inner porphyrins of the S-polymer and are strongly solvent-dependent. Thermodynamic analysis revealed that the formation of the E- or S-polymer in solution is determined by the total energies and the type of solvent used. The transformation of the E- to S-polymer was investigated by gel permeation chromatography. The kinetics of the transformation were also determined. The role of the terminal imidazolylporphyrinatozinc moieties was also investigated: The results indicate that the transformation from the E- to S-polymer occurs by an exchange mechanism between the polymers, induced by attack of terminal free imidazolyl groups on a polymer to zinc porphyrins on other polymers.","subitem_description_language":"en","subitem_description_type":"Abstract"}]},"item_10001_description_6":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"Bis(imidazolylporphyrinatozinc) molecules linked through a 1,3-butadiynylene moiety respond to the solvents they are dissolved in to afford exclusively extended (E) or stacked (S) supramolecular polymers. This system is expected to be a solvation/desolvation indicator. However, the principles underlying the solvent-dependent formation of the two types of polymers and the mechanism of the transformation between them are unclear. The formation of the polymers is considered to depend on the two types of complementary coordination bonds that can be formed and the π-π interactions between the porphyrins. In this study, the contributions and solvent dependence of both the coordination bonds and the π-π interactions have been investigated. The results clearly indicate that the coordination bonds are weakly or little solvent-dependent, and that the π-π interactions function effectively only in the inner porphyrins of the S-polymer and are strongly solvent-dependent. Thermodynamic analysis revealed that the formation of the E- or S-polymer in solution is determined by the total energies and the type of solvent used. The transformation of the E- to S-polymer was investigated by gel permeation chromatography. The kinetics of the transformation were also determined. The role of the terminal imidazolylporphyrinatozinc moieties was also investigated: The results indicate that the transformation from the E- to S-polymer occurs by an exchange mechanism between the polymers, induced by attack of terminal free imidazolyl groups on a polymer to zinc porphyrins on other polymers.","subitem_description_language":"en","subitem_description_type":"Other"}]},"item_10001_publisher_8":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"Wiley","subitem_publisher_language":"en"}]},"item_10001_relation_13":{"attribute_name":"PubMed番号","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"31618485","subitem_relation_type_select":"PMID"}}]},"item_10001_relation_14":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"10.1002/chem.201903608","subitem_relation_type_select":"DOI"}}]},"item_10001_rights_15":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"This is the peer reviewed version of the following article: Chemistry – A European Journal, 26(3), 669-684, which has been published in final form at https://doi.org/10.1002/chem.201903608. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions. The full-text file will be made open to the public on 22 January 2020 in accordance with publisher's 'Terms and Conditions for Self-Archiving' This is not the published version. Please cite only the published version. この論文は出版社版でありません。引用の際には出版社版をご確認ご利用ください。","subitem_rights_language":"en"}]},"item_10001_source_id_9":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"1521-3765","subitem_source_identifier_type":"PISSN"}]},"item_10001_version_type_20":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"佐竹, 彰治","creatorNameLang":"ja"},{"creatorName":"サタケ, アキハル","creatorNameLang":"ja-Kana"},{"creatorName":"Satake, Akiharu","creatorNameLang":"en"}]},{"creatorNames":[{"creatorName":"鈴木, 友樹","creatorNameLang":"ja"},{"creatorName":"スズキ, ユウキ","creatorNameLang":"ja-Kana"},{"creatorName":"Suzuki, Yuki","creatorNameLang":"en"}]},{"creatorNames":[{"creatorName":"杉本, 基伸","creatorNameLang":"ja"},{"creatorName":"スギモト, モトノブ","creatorNameLang":"ja-Kana"},{"creatorName":"Sugimoto, Motonobu","creatorNameLang":"en"}]},{"creatorNames":[{"creatorName":"倉持, 悠輔","creatorNameLang":"ja"},{"creatorName":"クラモチ, ユウスケ","creatorNameLang":"ja-Kana"},{"creatorName":"Kuramochi, Yusuke","creatorNameLang":"en"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2021-02-18"}],"displaytype":"detail","filename":"CEJ_manuscript accepted Mechanism Satake.pdf","filesize":[{"value":"1.5 MB"}],"format":"application/pdf","licensetype":"license_11","mimetype":"application/pdf","url":{"label":"CEJ_mechanistic study of the solvent-dependent ...","objectType":"fulltext","url":"https://tus.repo.nii.ac.jp/record/3631/files/CEJ_manuscript accepted Mechanism Satake.pdf"},"version_id":"fe3659a0-d911-47ef-a9be-be7cf9d2d71c"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"allostrism","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"gel permeation chromatography","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"polymers","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"porphyrinoids","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"supramolecular chemistry","subitem_subject_language":"en","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Mechanistic Study of the Solvent-Dependent Formation of Extended and Stacked Supramolecular Polymers Composed of Bis(imidazolylporphyrinatozinc) Molecules.","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Mechanistic Study of the Solvent-Dependent Formation of Extended and Stacked Supramolecular Polymers Composed of Bis(imidazolylporphyrinatozinc) Molecules.","subitem_title_language":"en"}]},"item_type_id":"10001","owner":"12","path":["402"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2021-02-08"},"publish_date":"2021-02-08","publish_status":"0","recid":"3631","relation_version_is_last":true,"title":["Mechanistic Study of the Solvent-Dependent Formation of Extended and Stacked Supramolecular Polymers Composed of Bis(imidazolylporphyrinatozinc) Molecules."],"weko_creator_id":"12","weko_shared_id":-1},"updated":"2023-11-08T02:30:27.230302+00:00"}