{"created":"2023-06-19T09:32:21.108943+00:00","id":2483,"links":{},"metadata":{"_buckets":{"deposit":"44416b22-7eb9-4006-97bf-8013680905ba"},"_deposit":{"created_by":12,"id":"2483","owners":[12],"pid":{"revision_id":0,"type":"depid","value":"2483"},"status":"published"},"_oai":{"id":"oai:tus.repo.nii.ac.jp:00002483","sets":["401:402"]},"author_link":[],"item_10001_biblio_info_7":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2015-08-10","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"33","bibliographicPageEnd":"11756","bibliographicPageStart":"11745","bibliographicVolumeNumber":"21","bibliographic_titles":[{"bibliographic_title":"Chemistry - A European Journal","bibliographic_titleLang":"en"}]}]},"item_10001_description_5":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"The one-step synthesis of D3h -symmetric cyclic porphyrin trimers 1 composed of three 2,2'-[4,4'-bis(methoxycarbonyl)]bipyridyl moieties and three porphyrinatozinc moieties was achieved from a nickel-mediated reductive coupling of meso-5,15-bis(6-chloro-4-methoxycarbonylpyrid-2-yl)porphyrinatozinc. Although cyclic trimers 1 were obtained as a mixture that included other cyclic and acyclic porphyrin oligomers, an extremely specific separation was observed only for cyclic trimers 1 when using columns of silica gel modified with pyrenylethyl, cyanopropyl, and other groups. Structural analysis of cyclic trimers 1 was carried out by means of NMR spectroscopy and X-ray crystallography. Treatment of an η(3) -allylpalladium complex with a cyclic trimer gave a tris(palladium) complex containing three η(3) -allylpalladium groups inside the space, which indicated that the bipyridyl moieties inside the ring could work as bidentate metalloligands. ","subitem_description_language":"en","subitem_description_type":"Abstract"}]},"item_10001_description_6":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"The one-step synthesis of D3h -symmetric cyclic porphyrin trimers 1 composed of three 2,2'-[4,4'-bis(methoxycarbonyl)]bipyridyl moieties and three porphyrinatozinc moieties was achieved from a nickel-mediated reductive coupling of meso-5,15-bis(6-chloro-4-methoxycarbonylpyrid-2-yl)porphyrinatozinc. Although cyclic trimers 1 were obtained as a mixture that included other cyclic and acyclic porphyrin oligomers, an extremely specific separation was observed only for cyclic trimers 1 when using columns of silica gel modified with pyrenylethyl, cyanopropyl, and other groups. Structural analysis of cyclic trimers 1 was carried out by means of NMR spectroscopy and X-ray crystallography. Treatment of an η(3) -allylpalladium complex with a cyclic trimer gave a tris(palladium) complex containing three η(3) -allylpalladium groups inside the space, which indicated that the bipyridyl moieties inside the ring could work as bidentate metalloligands. ","subitem_description_language":"en","subitem_description_type":"Other"}]},"item_10001_publisher_8":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"Wiley","subitem_publisher_language":"en"}]},"item_10001_relation_13":{"attribute_name":"PubMed番号","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"26178883","subitem_relation_type_select":"PMID"}}]},"item_10001_relation_18":{"attribute_name":"他の資源との関係","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"DOI:10.1002/chem.201501854"}]}]},"item_10001_rights_15":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"©2015 Wiley-VCHVerlag Gmbh & Co. KGaA,Weinheim　This is the peer reviewed version of the following artcle: https://onlinelibrary.wiley.com/doi/full/10.1002/chem.201501854, which has been published in final form at DOI:10.1002/chem.201501854.This artcle may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving.この論文は出版社版ではありません。引用の際には出版社版をご確認・ご利用下さい。","subitem_rights_language":"en"}]},"item_10001_source_id_9":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"1521-3765","subitem_source_identifier_type":"PISSN"}]},"item_10001_version_type_20":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"大古田, 燿平","creatorNameLang":"ja"},{"creatorName":"オオコダ, ヨウヘイ","creatorNameLang":"ja-Kana"},{"creatorName":"Ohkoda, Yohei","creatorNameLang":"en"}]},{"creatorNames":[{"creatorName":"浅石, 茜","creatorNameLang":"ja"},{"creatorName":"アサイシ, アカネ","creatorNameLang":"ja-Kana"},{"creatorName":"Asaishi, Akane","creatorNameLang":"en"}]},{"creatorNames":[{"creatorName":"並木, 智哉","creatorNameLang":"ja"},{"creatorName":"ナミキ, トモヤ","creatorNameLang":"ja-Kana"},{"creatorName":"Namiki, Tomoya","creatorNameLang":"en"}]},{"creatorNames":[{"creatorName":"橋本, 朋昭","creatorNameLang":"ja"},{"creatorName":"ハシモト, トモアキ","creatorNameLang":"ja-Kana"},{"creatorName":"Hashimoto, Tomoaki","creatorNameLang":"en"}]},{"creatorNames":[{"creatorName":"山田, 翠","creatorNameLang":"ja"},{"creatorName":"ヤマダ, ミドリ","creatorNameLang":"ja-Kana"},{"creatorName":"Yamada, Midori","creatorNameLang":"en"}]},{"creatorNames":[{"creatorName":"白井, 公一郎","creatorNameLang":"ja"},{"creatorName":"シライ, コウイチロウ","creatorNameLang":"ja-Kana"},{"creatorName":"Shirai, Koichiro","creatorNameLang":"en"}]},{"creatorNames":[{"creatorName":"片上, 勇太","creatorNameLang":"ja"},{"creatorName":"カタガミ, ユウタ","creatorNameLang":"ja-Kana"},{"creatorName":"Katagami, Yuta","creatorNameLang":"en"}]},{"creatorNames":[{"creatorName":"菅谷, 知明","creatorNameLang":"ja"},{"creatorName":"スガヤ, トモアキ","creatorNameLang":"ja-Kana"},{"creatorName":"Sugaya, Tomoaki","creatorNameLang":"en"}]},{"creatorNames":[{"creatorName":"田所, 誠","creatorNameLang":"ja"},{"creatorName":"タドコロ, マコト","creatorNameLang":"ja-Kana"},{"creatorName":"Tadokoro, Makoto","creatorNameLang":"en"}]},{"creatorNames":[{"creatorName":"佐竹, 彰治","creatorNameLang":"ja"},{"creatorName":"サタケ, アキハル","creatorNameLang":"ja-Kana"},{"creatorName":"Satake, Akiharu","creatorNameLang":"en"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2019-11-27"}],"displaytype":"detail","filename":"CEJ_2015_Ohkoda_accepted.pdf","filesize":[{"value":"1.6 MB"}],"format":"application/pdf","licensetype":"license_11","mimetype":"application/pdf","url":{"label":"CEJ_2015_Ohkoda_accepted","objectType":"fulltext","url":"https://tus.repo.nii.ac.jp/record/2483/files/CEJ_2015_Ohkoda_accepted.pdf"},"version_id":"9a6ebffa-33b9-4216-bb7a-eec756052c6c"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"column chromatography","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"macrocycles","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"multinuclear complex","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"porphyrinoids","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"synthesis design","subitem_subject_language":"en","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"D3h -Symmetric Porphyrin-Based Rigid Macrocyclic Ligands for Multicofacial Multinuclear Complexes in a One-Nanometer-Sized Cavity.","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"D3h -Symmetric Porphyrin-Based Rigid Macrocyclic Ligands for Multicofacial Multinuclear Complexes in a One-Nanometer-Sized Cavity.","subitem_title_language":"en"}]},"item_type_id":"10001","owner":"12","path":["402"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2019-10-03"},"publish_date":"2019-10-03","publish_status":"0","recid":"2483","relation_version_is_last":true,"title":["D3h -Symmetric Porphyrin-Based Rigid Macrocyclic Ligands for Multicofacial Multinuclear Complexes in a One-Nanometer-Sized Cavity."],"weko_creator_id":"12","weko_shared_id":-1},"updated":"2023-11-08T02:30:20.077010+00:00"}