{"created":"2023-06-19T09:32:21.066188+00:00","id":2482,"links":{},"metadata":{"_buckets":{"deposit":"98785d24-5cc4-41a8-8917-da29bbb610da"},"_deposit":{"created_by":12,"id":"2482","owners":[12],"pid":{"revision_id":0,"type":"depid","value":"2482"},"status":"published"},"_oai":{"id":"oai:tus.repo.nii.ac.jp:00002482","sets":["401:402"]},"author_link":[],"item_10001_biblio_info_7":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2018-10-01","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"55","bibliographicPageEnd":"14741","bibliographicPageStart":"14733","bibliographicVolumeNumber":"24","bibliographic_titles":[{"bibliographic_title":"Chemistry - A European Journal","bibliographic_titleLang":"en"}]}]},"item_10001_description_5":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"Solvation is a ubiquitous phenomenon associated with molecules in solutions. It often determines the equilibria of molecular systems and the rates of chemical reactions. Van der Waals interactions (a general term) includes weak interactions among noncharged compounds and it contributes significantly to solvation. The distinct observation of van der Waals interaction between solvent and porphyrin derivatives is reported herein. Bis(imidazolylporphyrinatozinc) structures connected through a 1,3-butadiyne moiety give two types of coordination polymers, E (extended) and S (stacked) polymers, exclusively. E polymers have larger solvent-accessible surface areas than the corresponding S polymers. Therefore, E polymers are better solvated than S polymers, providing an indicator of solvation and desolvation for the solvents used. A simple method (like a litmus test) was developed to evaluate the solvation ability of various solvents. Sixty-seven solvents and liquid compounds were tested, under the same conditions, using a conventional UV/Vis spectrometer. The results revealed a new liquid group with high solvation ability towards the porphyrins, and clarified van der Waals interaction assisted by secondary interaction on the substituents. The indicator system should contribute to the solution chemistry of molecules and materials, and to supramolecular chemistry interactions among hetero components.","subitem_description_language":"en","subitem_description_type":"Abstract"}]},"item_10001_description_6":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"Solvation is a ubiquitous phenomenon associated with molecules in solutions. It often determines the equilibria of molecular systems and the rates of chemical reactions. Van der Waals interactions (a general term) includes weak interactions among noncharged compounds and it contributes significantly to solvation. The distinct observation of van der Waals interaction between solvent and porphyrin derivatives is reported herein. Bis(imidazolylporphyrinatozinc) structures connected through a 1,3-butadiyne moiety give two types of coordination polymers, E (extended) and S (stacked) polymers, exclusively. E polymers have larger solvent-accessible surface areas than the corresponding S polymers. Therefore, E polymers are better solvated than S polymers, providing an indicator of solvation and desolvation for the solvents used. A simple method (like a litmus test) was developed to evaluate the solvation ability of various solvents. Sixty-seven solvents and liquid compounds were tested, under the same conditions, using a conventional UV/Vis spectrometer. The results revealed a new liquid group with high solvation ability towards the porphyrins, and clarified van der Waals interaction assisted by secondary interaction on the substituents. The indicator system should contribute to the solution chemistry of molecules and materials, and to supramolecular chemistry interactions among hetero components.","subitem_description_language":"en","subitem_description_type":"Other"}]},"item_10001_publisher_8":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"Wiley","subitem_publisher_language":"en"}]},"item_10001_relation_13":{"attribute_name":"PubMed番号","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"29989274","subitem_relation_type_select":"PMID"}}]},"item_10001_relation_18":{"attribute_name":"他の資源との関係","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"DOI:10.1002/chem.201802402"}]}]},"item_10001_rights_15":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"©2018 Wiley-VCHVerlag Gmbh & Co. KGaA,Weinheim　This is the peer reviewed version of the following artcle: https://onlinelibrary.wiley.com/doi/10.1002/chem.201802402, which has been published in final form at DOI:10.1002/chem.201802402.This artcle may be used fr non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving.","subitem_rights_language":"en"}]},"item_10001_source_id_9":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"1521-3765","subitem_source_identifier_type":"PISSN"}]},"item_10001_version_type_20":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"佐竹, 彰治","creatorNameLang":"ja"},{"creatorName":"サタケ, アキハル","creatorNameLang":"ja-Kana"},{"creatorName":"Satake, Akiharu","creatorNameLang":"en"}]},{"creatorNames":[{"creatorName":"鈴木, 友樹","creatorNameLang":"ja"},{"creatorName":"スズキ, ユウキ","creatorNameLang":"ja-Kana"},{"creatorName":"Suzuki, Yuki","creatorNameLang":"en"}]},{"creatorNames":[{"creatorName":"杉本, 基伸","creatorNameLang":"ja"},{"creatorName":"スギモト, モトノブ","creatorNameLang":"ja-Kana"},{"creatorName":"Sugimoto, Motonobu","creatorNameLang":"en"}]},{"creatorNames":[{"creatorName":"島崎, 巽","creatorNameLang":"ja"},{"creatorName":"シマザキ, タツミ","creatorNameLang":"ja-Kana"},{"creatorName":"Shimazaki, Tatsumi","creatorNameLang":"en"}]},{"creatorNames":[{"creatorName":"石井, 秀和","creatorNameLang":"ja"},{"creatorName":"イシイ, ヒデカズ","creatorNameLang":"ja-Kana"},{"creatorName":"Ishii, Hidekazu","creatorNameLang":"en"}]},{"creatorNames":[{"creatorName":"倉持, 悠輔","creatorNameLang":"ja"},{"creatorName":"クラモチ, ユウスケ","creatorNameLang":"ja-Kana"},{"creatorName":"Kuramochi, Yusuke","creatorNameLang":"en"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2019-10-24"}],"displaytype":"detail","filename":"CEJ_2018_Satake_Solvation_Accepted.pdf","filesize":[{"value":"1.0 MB"}],"format":"application/pdf","licensetype":"license_11","mimetype":"application/pdf","url":{"label":"CEJ_2018_Satake_Solvation_Accepted","objectType":"fulltext","url":"https://tus.repo.nii.ac.jp/record/2482/files/CEJ_2018_Satake_Solvation_Accepted.pdf"},"version_id":"d3cd5933-6068-42bc-96bd-faeedb5e2563"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"non-bonding interactions","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"polymers","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"porphyrins","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"solvation","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"supramolecular chemistry","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"non-bonding interactions","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"polymers","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"porphyrins","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"solvation","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"supramolecular chemistry","subitem_subject_language":"en","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"A Solvation/Desolvation Indicator Based on van der Waals Interactions between Solvents and Porphyrins.","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"A Solvation/Desolvation Indicator Based on van der Waals Interactions between Solvents and Porphyrins.","subitem_title_language":"en"}]},"item_type_id":"10001","owner":"12","path":["402"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2019-10-03"},"publish_date":"2019-10-03","publish_status":"0","recid":"2482","relation_version_is_last":true,"title":["A Solvation/Desolvation Indicator Based on van der Waals Interactions between Solvents and Porphyrins."],"weko_creator_id":"12","weko_shared_id":-1},"updated":"2023-11-08T02:30:22.680298+00:00"}