@article{oai:tus.repo.nii.ac.jp:00002482,
 author = {佐竹, 彰治 and Satake, Akiharu and 鈴木, 友樹 and Suzuki, Yuki and 杉本, 基伸 and Sugimoto, Motonobu and 島崎, 巽 and Shimazaki, Tatsumi and 石井, 秀和 and Ishii, Hidekazu and 倉持, 悠輔 and Kuramochi, Yusuke},
 issue = {55},
 journal = {Chemistry - A European Journal},
 month = {Oct},
 note = {Solvation is a ubiquitous phenomenon associated with molecules in solutions. It often determines the equilibria of molecular systems and the rates of chemical reactions. Van der Waals interactions (a general term) includes weak interactions among noncharged compounds and it contributes significantly to solvation. The distinct observation of van der Waals interaction between solvent and porphyrin derivatives is reported herein. Bis(imidazolylporphyrinatozinc) structures connected through a 1,3-butadiyne moiety give two types of coordination polymers, E (extended) and S (stacked) polymers, exclusively. E polymers have larger solvent-accessible surface areas than the corresponding S polymers. Therefore, E polymers are better solvated than S polymers, providing an indicator of solvation and desolvation for the solvents used. A simple method (like a litmus test) was developed to evaluate the solvation ability of various solvents. Sixty-seven solvents and liquid compounds were tested, under the same conditions, using a conventional UV/Vis spectrometer. The results revealed a new liquid group with high solvation ability towards the porphyrins, and clarified van der Waals interaction assisted by secondary interaction on the substituents. The indicator system should contribute to the solution chemistry of molecules and materials, and to supramolecular chemistry interactions among hetero components., Solvation is a ubiquitous phenomenon associated with molecules in solutions. It often determines the equilibria of molecular systems and the rates of chemical reactions. Van der Waals interactions (a general term) includes weak interactions among noncharged compounds and it contributes significantly to solvation. The distinct observation of van der Waals interaction between solvent and porphyrin derivatives is reported herein. Bis(imidazolylporphyrinatozinc) structures connected through a 1,3-butadiyne moiety give two types of coordination polymers, E (extended) and S (stacked) polymers, exclusively. E polymers have larger solvent-accessible surface areas than the corresponding S polymers. Therefore, E polymers are better solvated than S polymers, providing an indicator of solvation and desolvation for the solvents used. A simple method (like a litmus test) was developed to evaluate the solvation ability of various solvents. Sixty-seven solvents and liquid compounds were tested, under the same conditions, using a conventional UV/Vis spectrometer. The results revealed a new liquid group with high solvation ability towards the porphyrins, and clarified van der Waals interaction assisted by secondary interaction on the substituents. The indicator system should contribute to the solution chemistry of molecules and materials, and to supramolecular chemistry interactions among hetero components.},
 pages = {14733--14741},
 title = {A Solvation/Desolvation Indicator Based on van der Waals Interactions between Solvents and Porphyrins.},
 volume = {24},
 year = {2018},
 yomi = {サタケ, アキハル and スズキ, ユウキ and スギモト, モトノブ and シマザキ, タツミ and イシイ, ヒデカズ and クラモチ, ユウスケ}
}