{"_buckets": {"deposit": "44416b22-7eb9-4006-97bf-8013680905ba"}, "_deposit": {"created_by": 12, "id": "2483", "owners": [12], "pid": {"revision_id": 0, "type": "depid", "value": "2483"}, "status": "published"}, "_oai": {"id": "oai:tus.repo.nii.ac.jp:00002483", "sets": ["402"]}, "author_link": [], "item_10001_biblio_info_7": {"attribute_name": "書誌情報", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2015-08-10", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "33", "bibliographicPageEnd": "11756", "bibliographicPageStart": "11745", "bibliographicVolumeNumber": "21", "bibliographic_titles": [{"bibliographic_title": "Chemistry - A European Journal", "bibliographic_titleLang": "en"}]}]}, "item_10001_description_5": {"attribute_name": "抄録", "attribute_value_mlt": [{"subitem_description": "The one-step synthesis of D3h -symmetric cyclic porphyrin trimers 1 composed of three 2,2\u0027-[4,4\u0027-bis(methoxycarbonyl)]bipyridyl moieties and three porphyrinatozinc moieties was achieved from a nickel-mediated reductive coupling of meso-5,15-bis(6-chloro-4-methoxycarbonylpyrid-2-yl)porphyrinatozinc. Although cyclic trimers 1 were obtained as a mixture that included other cyclic and acyclic porphyrin oligomers, an extremely specific separation was observed only for cyclic trimers 1 when using columns of silica gel modified with pyrenylethyl, cyanopropyl, and other groups. Structural analysis of cyclic trimers 1 was carried out by means of NMR spectroscopy and X-ray crystallography. Treatment of an η(3) -allylpalladium complex with a cyclic trimer gave a tris(palladium) complex containing three η(3) -allylpalladium groups inside the space, which indicated that the bipyridyl moieties inside the ring could work as bidentate metalloligands. ", "subitem_description_language": "en", "subitem_description_type": "Abstract"}]}, "item_10001_description_6": {"attribute_name": "内容記述", "attribute_value_mlt": [{"subitem_description": "The one-step synthesis of D3h -symmetric cyclic porphyrin trimers 1 composed of three 2,2\u0027-[4,4\u0027-bis(methoxycarbonyl)]bipyridyl moieties and three porphyrinatozinc moieties was achieved from a nickel-mediated reductive coupling of meso-5,15-bis(6-chloro-4-methoxycarbonylpyrid-2-yl)porphyrinatozinc. Although cyclic trimers 1 were obtained as a mixture that included other cyclic and acyclic porphyrin oligomers, an extremely specific separation was observed only for cyclic trimers 1 when using columns of silica gel modified with pyrenylethyl, cyanopropyl, and other groups. Structural analysis of cyclic trimers 1 was carried out by means of NMR spectroscopy and X-ray crystallography. Treatment of an η(3) -allylpalladium complex with a cyclic trimer gave a tris(palladium) complex containing three η(3) -allylpalladium groups inside the space, which indicated that the bipyridyl moieties inside the ring could work as bidentate metalloligands. ", "subitem_description_language": "en", "subitem_description_type": "Other"}]}, "item_10001_publisher_8": {"attribute_name": "出版者", "attribute_value_mlt": [{"subitem_publisher": "Wiley", "subitem_publisher_language": "en"}]}, "item_10001_relation_13": {"attribute_name": "PubMed番号", "attribute_value_mlt": [{"subitem_relation_type": "isVersionOf", "subitem_relation_type_id": {"subitem_relation_type_id_text": "26178883", "subitem_relation_type_select": "PMID"}}]}, "item_10001_relation_18": {"attribute_name": "他の資源との関係", "attribute_value_mlt": [{"subitem_relation_name": [{"subitem_relation_name_text": "DOI:10.1002/chem.201501854"}]}]}, "item_10001_rights_15": {"attribute_name": "権利", "attribute_value_mlt": [{"subitem_rights": "©2015 Wiley-VCHVerlag Gmbh \u0026 Co. KGaA,Weinheim This is the peer reviewed version of the following artcle: https://onlinelibrary.wiley.com/doi/full/10.1002/chem.201501854, which has been published in final form at DOI:10.1002/chem.201501854.This artcle may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving.この論文は出版社版ではありません。引用の際には出版社版をご確認・ご利用下さい。", "subitem_rights_language": "en"}]}, "item_10001_source_id_9": {"attribute_name": "ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "1521-3765", "subitem_source_identifier_type": "PISSN"}]}, "item_10001_version_type_20": {"attribute_name": "著者版フラグ", "attribute_value_mlt": [{"subitem_version_resource": "http://purl.org/coar/version/c_ab4af688f83e57aa", "subitem_version_type": "AM"}]}, "item_creator": {"attribute_name": "著者", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "大古田, 燿平", "creatorNameLang": "ja"}, {"creatorName": "オオコダ, ヨウヘイ", "creatorNameLang": "ja-Kana"}, {"creatorName": "Ohkoda, Yohei", "creatorNameLang": "en"}]}, {"creatorNames": [{"creatorName": "浅石, 茜", "creatorNameLang": "ja"}, {"creatorName": "アサイシ, アカネ", "creatorNameLang": "ja-Kana"}, {"creatorName": "Asaishi, Akane", "creatorNameLang": "en"}]}, {"creatorNames": [{"creatorName": "並木, 智哉", "creatorNameLang": "ja"}, {"creatorName": "ナミキ, トモヤ", "creatorNameLang": "ja-Kana"}, {"creatorName": "Namiki, Tomoya", "creatorNameLang": "en"}]}, {"creatorNames": [{"creatorName": "橋本, 朋昭", "creatorNameLang": "ja"}, {"creatorName": "ハシモト, トモアキ", "creatorNameLang": "ja-Kana"}, {"creatorName": "Hashimoto, Tomoaki", "creatorNameLang": "en"}]}, {"creatorNames": [{"creatorName": "山田, 翠", "creatorNameLang": "ja"}, {"creatorName": "ヤマダ, ミドリ", "creatorNameLang": "ja-Kana"}, {"creatorName": "Yamada, Midori", "creatorNameLang": "en"}]}, {"creatorNames": [{"creatorName": "白井, 公一郎", "creatorNameLang": "ja"}, {"creatorName": "シライ, コウイチロウ", "creatorNameLang": "ja-Kana"}, {"creatorName": "Shirai, Koichiro", "creatorNameLang": "en"}]}, {"creatorNames": [{"creatorName": "片上, 勇太", "creatorNameLang": "ja"}, {"creatorName": "カタガミ, ユウタ", "creatorNameLang": "ja-Kana"}, {"creatorName": "Katagami, Yuta", "creatorNameLang": "en"}]}, {"creatorNames": [{"creatorName": "菅谷, 知明", "creatorNameLang": "ja"}, {"creatorName": "スガヤ, トモアキ", "creatorNameLang": "ja-Kana"}, {"creatorName": "Sugaya, Tomoaki", "creatorNameLang": "en"}]}, {"creatorNames": [{"creatorName": "田所, 誠", "creatorNameLang": "ja"}, {"creatorName": "タドコロ, マコト", "creatorNameLang": "ja-Kana"}, {"creatorName": "Tadokoro, Makoto", "creatorNameLang": "en"}]}, {"creatorNames": [{"creatorName": "佐竹, 彰治", "creatorNameLang": "ja"}, {"creatorName": "サタケ, アキハル", "creatorNameLang": "ja-Kana"}, {"creatorName": "Satake, Akiharu", "creatorNameLang": "en"}]}]}, "item_files": {"attribute_name": "ファイル情報", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2019-11-27"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "CEJ_2015_Ohkoda_accepted.pdf", "filesize": [{"value": "1.6 MB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_11", "mimetype": "application/pdf", "size": 1600000.0, "url": {"label": "CEJ_2015_Ohkoda_accepted", "objectType": "fulltext", "url": "https://tus.repo.nii.ac.jp/record/2483/files/CEJ_2015_Ohkoda_accepted.pdf"}, "version_id": "9a6ebffa-33b9-4216-bb7a-eec756052c6c"}]}, "item_keyword": {"attribute_name": "キーワード", "attribute_value_mlt": [{"subitem_subject": "column chromatography", "subitem_subject_language": "en", "subitem_subject_scheme": "Other"}, {"subitem_subject": "macrocycles", "subitem_subject_language": "en", "subitem_subject_scheme": "Other"}, {"subitem_subject": "multinuclear complex", "subitem_subject_language": "en", "subitem_subject_scheme": "Other"}, {"subitem_subject": "porphyrinoids", "subitem_subject_language": "en", "subitem_subject_scheme": "Other"}, {"subitem_subject": "synthesis design", "subitem_subject_language": "en", "subitem_subject_scheme": "Other"}]}, "item_language": {"attribute_name": "言語", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "資源タイプ", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "D3h -Symmetric Porphyrin-Based Rigid Macrocyclic Ligands for Multicofacial Multinuclear Complexes in a One-Nanometer-Sized Cavity.", "item_titles": {"attribute_name": "タイトル", "attribute_value_mlt": [{"subitem_title": "D3h -Symmetric Porphyrin-Based Rigid Macrocyclic Ligands for Multicofacial Multinuclear Complexes in a One-Nanometer-Sized Cavity.", "subitem_title_language": "en"}]}, "item_type_id": "10001", "owner": "12", "path": ["402"], "permalink_uri": "https://tus.repo.nii.ac.jp/records/2483", "pubdate": {"attribute_name": "PubDate", "attribute_value": "2019-10-03"}, "publish_date": "2019-10-03", "publish_status": "0", "recid": "2483", "relation": {}, "relation_version_is_last": true, "title": ["D3h -Symmetric Porphyrin-Based Rigid Macrocyclic Ligands for Multicofacial Multinuclear Complexes in a One-Nanometer-Sized Cavity."], "weko_shared_id": -1}
D3h -Symmetric Porphyrin-Based Rigid Macrocyclic Ligands for Multicofacial Multinuclear Complexes in a One-Nanometer-Sized Cavity.
https://tus.repo.nii.ac.jp/records/2483
https://tus.repo.nii.ac.jp/records/2483